CONTACT

Lorenzo Carbone PhD Student

Sapienza University, Rome

Chemistry Department

Piazzale Aldo Moro n°5 00185 Rome Italy

Phone : +39 49913664

e-mail : lorenzo.carbone@uniroma1.it

Carbone Lorenzo  New Generation of Energy Storage Devices
SUPERVISOR

Professor Jusef Hassoun

Ferrara University, Ferrara

Chemistry Department

Via Fossato di mortara 17, Ferrara, Italy

Phone : +39 0532455163

e-mail : Jusef.Hassoun@unife.it

Mail: lorenzo.carbone@uniroma1.it Mail: jusef.hassoun@unife.it Home
Home Research Articles Conference Collaborations About Me

Lorenzo Carbone,†a Roberta Verrelli,†a Mallory Gobet,‡ Jing Peng,‡§ Matthew Devany,∥ Bruno Scrosati,⊥ Steve Greenbaum,*‡ and Jusef Hassoun*°

a Author equally contributed.

†Chemistry Department, Sapienza University of Rome, Piazzale Aldo Moro, 5, 00185, Rome, Italy

‡Department of Physics & Astronomy, Hunter College of the City University of New York, New York, New York 10065, USA. E-mail: steve.greenbaum@hunter.cuny.edu  

§cPhD Program in Chemistry, City University of New York, New York, NY 10016, USA

∥Department of Chemistry and Biochemistry, Hunter College of the City University of New York, New York, New York 10065, USA  

⊥Electtrochimica ed Energia, Rome, Italy

° Department of Chemical and Pharmaceutical Sciences, Chemistry, University of Ferrara, Via Fossato di Mortara, 17, 44121, Ferrara, Italy. E-mail: jusef.hassoun@unife.it

INSIGHT ON THE LI2S ELECTROCHEMICAL PROCESS IN A COMPOSITE CONFIGURATION ELECTRODE

ABSTRACT: A novel, low cost and environmentally sustainable lithium sulfide–carbon composite cathode, suitably prepared by combining polyethylene oxide (PEO), LiCF3SO3 and Li2S–C powders is presented herein. The cathode is characterized in a lithium-metal cell employing a solution of LiCF3SO3 salt in dioxolane– dimethylether (DOL:DME) as the electrolyte. The detailed NMR investigation of the diffusion properties of the electrolyte is reported in order to determine its suitability for the proposed cell. The addition of LiNO3 to the electrolyte solution allows its practical application in a lithium sulfur cell using an Li2S–C-based cathode characterized by a specific capacity of about 500 mA h g1 (with respect to the Li2S mass). The cell holds its optimal performances for over 70 cycles at a C/5 rate, with a steady state efficiency approaching 99%. The X-ray diffraction patterns of the cell upon operation suggest the reversibility of the Li2S electrochemical process, while the repeated electrochemical impedance spectroscopy (EIS) measurements indicate the suitability of the electrode–electrolyte interface in terms of low and stable cell impedance. Furthermore, the EIS study clarifies the activation process occurring at the Li2S cathode during the first charge process, leading to a decrease of cell polarization during the following cycles. The data reported here shed light on important aspects which should be considered for the efficient application of a Li2S cathode in lithium batteries.


Insight on the Li2S electrochemical process in a composite configuration electrode


New J. Chem.


The Royal Society of Chemistry


View at Publisher

DOI: DOI:10.1039/c5nj03402g